From Independent Research at ISU (*Denotes corresponding author)

A complete and updated list of publications is also available at Google Scholar.

2019

88. Gvozdetskyi V., Bhaskar G., Batuk M., Zhao X., Carnahan S.L., Hanrahan M.P., Ribeiro R.A., Canfield P.C., Rossini A.J., Wang C.-Z., Ho K.-M., Hadermann J., Zaikina J.V.* Computationally-driven discovery of 2D MBene layers in the family of LiNiB polymorphs, Angew. Chem. Int. Ed., 2019, DOI:10.1002/anie.201907499.

87. Carnahan S.L., Venkatesh A., Perras F.A., Wishart J.F. and Rossini A.J.* Magic Angle Spinning Dynamic Nuclear Polarization With Radicals Created by γ-Irradiation, J. Phys. Chem. Lett, 2019, DOI:10.1021/acs.jpclett.9b01655.

86. Chang B.S., Thomas B., Chen J., Tevis I., Oyola-Reynoso S., Çınar S, Rossini A.J.,* Thuo M.* Ambient Synthesis of Coordination Polymer Nanomaterials by in situ Heterogeneous Metal/Ligand reactions (HetMet), Nanoscale, 2019, 11, 14060-14069, DOI: 10.1039/C9NR05448K.

85. Venkatesh A., Wijesekara A.V., O’Dell L.A., Rossini. A.J.* Comment on “Chirality-Induced Electron Spin Polarization and Enantiospecific Response in Solid-State Cross-Polarization Nuclear Magnetic Resonance”, ACS Nano, 2019, DOI:10.1021/acsnano.9b00221.

84. Hirsh D.A., Wijesekara A.V., Carnahan S.L., Hung I., Lubach J.W.,* Nagapudi K.,* Rossini A.J.* Rapid Characterization of Formulated Pharmaceuticals Using Fast MAS 1H Solid‑State NMR Spectroscopy, Mol. Pharm., 2019, DOI: 10.1021/acs.molpharmaceut.9b00343.

83. Mark J., Hanrahan M.P., Woo K.E., Lee S., Rossini A.J., Kovnir K.* Chemical and Electrochemical Lithiation of van der Waals Tetrel Arsenides, Chem. Eur. J., 2019, 25, 6392-6401, DOI: 10.1002/chem.201900339.

82. Gvozdetskyi V., Hanrahan M.P., Ribeiro R.A., Kim T., Zhou L., Rossini A.J., Canfield P.C., Zaikina J.V.* A Hydride Route to Alkali Metal Borides: A Case Study of Lithium Nickel Boride, Chem. Eur. J., 2019, 5, 4123 –4135, DOI:10.1002/chem.201805398.

81. Schmidt B.M., Pindwal A., Venkatesh A., Ellern A., Rossini A.J., Sadow A.D.*, Zwitterionic Trivalent (Alkyl)Lanthanide Complexes in Ziegler-type Butadiene Polymerization, ACS Catalysis, 2019, 9, 827–838, DOI:10.1021/acscatal.8b04025.

80. Carnahan S.L., Lampkin B.J., Naik P., Hanrahan M.P., Slowing I.I., Vanveller B., Wu G., Rossini A.J.* Probing O-H Bonding Through Proton Detected 1H-17O Double Resonance Solid-State NMR Spectroscopy, J. Am. Chem. Soc., 2019, 141, 441-450,  DOI10.1021/jacs.8b10878.

79. Love A.M., Thomas B., Specht S.E., Hanrahan M.P., Venegas J.M., Burt S.P, Grant J.T., Cendejas M.C., McDermott W.P., Rossini A.J.,* Hermans I.* Probing the Transformation of Boron Nitride Catalysts under Oxidative Dehydrogenation Conditions, J. Am. Chem. Soc., 2019, 141, 181-190, DOI10.1021/jacs.8b08165.

2018

78. Hanrahan M.P., Men L., Rosales B.A., Vela J.,* Rossini A.J.* Sensitivity-Enhanced 207Pb Solid-State NMR Spectroscopy for the Rapid, Non-Destructive Characterization of Organolead Halide Perovskites, Chem. Mater., 2018, 30, 7005-7015, DOI:10.1021/acs.chemmater.8b01899.

77. Stein J.L., Holden W., Venkatesh A., Mundy M.E., Rossini A.J., Seidler G.T.* and Cossairt B.M.* Probing Surface Defects of InP Quantum Dots Using Phosphorus Kα and Kβ X-ray Emission Spectroscopy, Chem. Mater., 201830, 6377-6388, DOI: 10.1021/acs.chemmater.8b02590.

76. White M.A., Baumler K.J., Chen Y., Venkatesh A., Medina-Gonzalez A.M., Rossini A.J., Zaikina J.V., Chan E.M., Vela J.* Expanding the I-II-V Phase Space: Soft Synthesis Investigation of Polytypic Ternary and Binary Zinc Antimonides, Chem. Mater., 201830, 6173-6182, DOI: 10.1021/acs.chemmater.8b02910.

75. Rossini A.J.* Materials Characterization by Dynamic Nuclear Polarization Enhanced Solid-State NMR Spectroscopy, J. Phys. Chem. Lett., 2018, 9, 5150–5159, DOI: 10.1021/acs.jpclett.8b01891. (Invited Perspective)

74. Nguyen Y., Lampkin B., Venkatesh A., Ellern A., Rossini A.J., VanVeller B.* Open Resonance Assisted Hydrogen Bonds and Competing Quasiaromaticity, J. Org. Chem839850–9857, DOI: 10.1021/acs.joc.8b01331.

73. Venkatesh A., Ryan M.J., Biswas A.,Boteju K.C., Sadow A.D., Rossini A.J.* Enhancing the Sensitivity of Solid-State NMR Experiments with Very Low-Gyromagnetic Ratio Nuclei with Fast MAS and Proton Detection, J. Phys. Chem. A, 2018, 122, 5635–5643, DOI10.1021/acs.jpca.8b05107.

72. Boteju K.C., Wan S., Venkatesh A., Ellern A., Rossini A.J., Sadow A.D.*  Rare Earth Arylsilazido Compounds with Inequivalent Secondary Interactions, Chem. Commun., 201854, 7318-7321, DOI10.1039/C8CC03186J.

71. Zhao L., Hanrahan M.P, Chakravarty P., DiPasquale A.G., Sirois L.E., Nagapudi K.,* Lubach J.W.,* Rossini A.J.* Characterization of Pharmaceutical Cocrystals and Salts by Dynamic Nuclear Polarization-Enhanced Solid-State NMR Spectroscopy, Cryst. Growth Des., 2018, 18, 2588–2601, DOI: 10.1021/acs.cgd.8b00203.

70. Pfennig T., Chemburkar A., Johnson R.L., Ryan M.J., Rossini A.J., Matthew Neurock, Shanks B.H.*, Modulating Activity and Selectivity of 2-Pyrone-Derived Bicyclic Lactones Through Choice of Catalyst and Solvent, ACS Catalysis, 2018, 8, 2450-2463, DOI: 10.1021/acscatal.7b04311.

69. Zhao Li, Pinon A.C., Emsley L., Rossini A.J.* DNP-Enhanced Solid-State NMR Spectroscopy of Active Pharmaceutical Ingredients, Magn. Reson. Chem., 2018, In Press, DOI: 10.1002/mrc.4688. (Special Issue on Hyper-polarization)

2017

68. Hanrahan M.P., Fought E.L., Windus T.L., Wheeler L.M., Anderson N.C., Neale N.R.*, Rossini A.J.* Characterization of Silicon Nanocrystal Surfaces by Multidimensional Solid-State NMR Spectroscopy, Chem. Mater., 2017, 29, 10339–10351, DOI: 10.1021/acs.chemmater.7b03306.

 

67. Hanrahan M.P., Venkatesh A., Carnahan S., Calahan J.L., Lubach J., Munson E.J.,* Rossini A.J.* Enhancing the Resolution of 1H and 13C Solid-State NMR Spectra by Reduction of Anisotropic Bulk Magnetic Susceptibility Broadening, Phys. Chem. Chem. Phys, 2017, 19, 28153-28162, DOI: 10.1039/C7CP04223J.

66. Carrero C.A., Burt S.P., Huang F., Venegas J.M., Love A.M., Mueller P., Zhu H., Grant J.T., Mathison R., Hanrahan M.P., Rossini A.J., Ball M., Dumesic J., Hermans I.* Supported Two- and Three-Dimensional Vanadium Oxide Species on the Surface of β-SiC, Catal. Sci. Techn., 2017, 7, 3707–3714, DOI:10.1039/C7CY01036B.

65. Johnson R.L., Hanrahan M.P., Mellmer M.A., Dumesic J.A., Rossini A.J., Shanks B.H.* The Solvent-Solid Interface of Acid Catalysts Studied by High Resolution MAS NMR, J. Phys. Chem. C, 2017, 121, 17226–17234, DOI: 10.1021/acs.jpcc.7b04102.

64. Nan H., Zhang C., Venkatesh A., Rossini A.J., Anderson J.L.* Argentation gas chromatography revisited: Separation of light olefin/paraffin mixtures using silver-based ionic liquid stationary phases, J. Chromatogr. A, 2017, 1523, 316-320, DOI:10.1016/j.chroma.2017.06.024

63. Venkatesh A., Hanrahan M.P., Rossini A.J.* Proton Detection of MAS Solid-State NMR Spectra of Half-Integer Quadrupolar Nuclei, Solid State Nuclear Magnetic Resonance, 2017, 84, 171-181, DOI:10.1016/j.ssnmr.2017.03.005.

62. Rosales B.A., Hanrahan M.P., Boote B.W., Rossini A.J.,* Smith E.A.,* Vela J.* Lead Halide Perovskites: Challenges and Opportunities in Advanced Synthesis and Spectroscopy, ACS Energy Letters, 2017, 2, 906-914, DOI: 10.1021/acsenergylett.6b00674.

nz-2016-00674g_0007

61. Perras F.A., Venkatesh A., Hanrahan M.P., Goh T.W., Huang W., Rossini A.J., Pruski M.* Indirect Detection of Infinite-Speed MAS Solid-State NMR Spectra, J. Magn. Reson., 2017, 276, 95-102, DOI:10.1016/j.jmr.2017.01.010. (Cover Article)

60. Nelson N.C., Boote B.W., Rossini A.J., Smith E.A., Slowing I.I.* Transfer Hydrogenation Activity over Sodium-Modified Ceria: Enrichment of Redox Sites Active for Alcohol Dehydrogenation, J. Catal., 2017, 346, 180-187, DOI: 10.1016/j.jcat.2016.12.018.

2016

59. Hirsh D.A., Rossini A.J.,* Emlsey L., Schurko R.W.,* 35Cl Dynamic Nuclear Polarization Solid-State NMR of Active Pharmaceutical Ingredients, Physical Chemistry Chemical Physics, 2016, 18, 25893-25904, DOI: 10.1039/C6CP04353D.

58. Rossini A.J.,* Hanrahan M.P., Thuo M., Rapid Acquisition of Wideline MAS Solid-state NMR Spectra with Fast MAS, Proton Detection, and Dipolar HMQC Pulse Sequences, Physical Chemistry Chemical Physics, 2016, 18, 25284-25295, DOI: 10.1039/C6CP04279A.

57. Rosales B.A., Men L., Cady S.D., Hanrahan M.P., Rossini A.J., Vela J.*, Persistent Dopants and Amorphous Phases in Organolead Halide Perovskites, Chemistry of Materials, 2016, 28 , 6848-6859, DOI: 10.1021/acs.chemmater.6b01874.

Publications From Post-Doc, PhD and Undergraduate Work:

56. Walder B.J., Berk C., Liao W.-C., Rossini A.J., Schwarzwälder M., Pradere U., Hall J., Lesage A., Copéret C., Emsley L.* One- and Two-Dimensional High-Resolution NMR from Flat Surfaces, 2019, ACS Central Science, 5, 515–523, DOI: 10.1021/acscentsci.8b00916.

55. Wisser D., Karthikeyan G., Lund A., Casano G., Karoui H., Yulikov M., Menzildjian G., Pinon A.C., Purea A., Engelke F., Chaudhari S.R., Kubicki D., Rossini A.J., Gajan D., Copéret C., Jeschke G., Lelli M.,* Emsley L.,* Lesage A.,* Ouari O.* BDPA-Nitroxide Biradicals for Efficient Dynamic Nuclear Polarization Enhanced Solid-State NMR at Magnetic Fields up to 21.1 T, J. Am. Chem. Soc., 2018, 140, 13340-13349, DOI: 10.1021/jacs.8b08081.

54. Viger-Gravel J., Schantz A., Pinon A.C., Rossini A.J., Schantz S., Emsley L. Structure of Lipid Nanoparticles Containing siRNA or mRNA by Dynamic Nuclear Polarization Enhanced NMR Spectroscopy, J. Phys. Chem. B., 2018122, 2073-2081, DOI: 10.1021/acs.jpcb.7b10795.

53. James J., Haies I., Lelli M., Rossini A.J., Kuprov I., Carravetta M. and Williamson P. Measurement of 14N Quadrupole Couplings in Biomolecular Solids Using Indirect-Detection 14N Solid-State NMR with DNP, Chem. Commun., 2017, 53, 12116-12119, DOI: 10.1039/c7cc03462h.

52. Pinon A.C., Schlagnitweit J., Berruyer P., Rossini A.J., Lelli M., Socie E., Tang M., Pham T.N., Lesage A., Schantz S. and Lyndon Emsley. Measuring Nano to Micro Structures From Relayed DNP NMR, J. Phys. Chem. C, 2017, 121, 15993–16005, DOI: 10.1021/acs.jpcc.

51. Kumar A., Walder B.J., Aslam K.M., Hofstetter A., Bhuvanesh S., Rossini A.J., Scrivener K., Emsley L., Bowen P. The Atomic-Level Structure of Cementitious Calcium Silicate Hydrate, J. Phys. Chem. C., 2017, 121, 17188–17196, DOI: 10.1021/acs.jpcc.7b02439.

50. Delley M.F., Lapadula G., Nunez-Zarur F., Comas-Vives A., Kalendra V., Jeschke G., Baabe D., Walter M.D., Rossini A.J., Lesage A., Emsley L., Maury O. and Copéret C. Local Structures and Heterogeneity of Silica-Supported M(III) Sites Evidenced by EPR, IR, NMR and Luminescence Spectroscopies, J. Am. Chem. Soc., 2017, 39, 8855–8867, DOI: 10.1021/jacs.7b02179.

49. Yarava J.R., Chaudhari S.R., Rossini A.J., Lesage A., Emsley L. Solvent Suppression in DNP Enhanced Solid State NMR, J. Magn. Reson., 2017, 277, 149–153, DOI:10.1016/j.jmr.2017.02.016.

48. Ji X., Bornet A., Vuichod B., Milani J., Gajan D., Rossini A.J., Emsley L., Bodenhausen G., Jannin S. Transportable Hyperpolarized Metabolites, Nature Communications, 2017, Article 13975, DOI:10.1038/ncomms13975.

47. Alphazan T., Mathey L., Schwarzwälder M., Lin T.-H., Rossini A.J., Wischert R., Enyedi V., Fontaine H., Veillerot M., Lesage A., Emsley L., Veyre L., Martin F., Thieuleux C., Copéret C., Monolayer Doping of Silicon through Grafting a Tailored Molecular Phosphorus Precursor onto Oxide-Passivated Silicon Surfaces, Chemistry of Materials, 2016, 28, 3634–3640.

46. Wolf P., Valla M., , Núñez-Zarur F., Comas-Vives A., Rossini A.J., Firth C., Kallas H., Lesage A., Emsley L., Copéret C., Hermans I. Correlating Synthetic Methods, Morphology, Atomic-Level Structure and Catalytic Activity of Sn-β Catalysts, ACS Catalysis, 2016, 6, 4047–4063.

45. Leclaire J., Poisson G., Ziarelli F., Pepe G., Fotiadu F., Paruzzo F.M., Rossini A.J., Dumez J.-N., Elena-Herrmann B. and Emsley L. Structure Elucidation of a Complex CO2-based Organic Framework Material by NMR Crystallography, Chemical Science, 2016, 7, 4379-4390.

44. Kubicki D.J., Casano G., Schwarzwälder M., Abel S., Sauvée C., Ganesan K., Yulikov M., Rossini A.J., Jeschke G., Copéret C., Lesage A., Tordo P., Ouari O., Emsley L., Rational Design of Dinitroxide Biradicals for Efficient Cross-Effect Dynamic Nuclear Polarization, Chemical Science, 2016, 7, 550-558.

43. Lelli M., Chaudari S., Gajan D., Casano G., Rossini A.J., Ouari O., Tordo P., Lesage A., Emsley L. Solid-State Dynamic Nuclear Polarization at 9.4 and 18.8 T from 100 K to Room Temperature, J. Am. Chem. Soc., 2015, 137, 14558–14561.

42. Piveteau L., Ong T.-C., Rossini A.J., Emsley L., Copéret C., Kovalenko M.K. The Structure of Colloidal Quantum Dots from Dynamic Nuclear Polarization Surface Enhanced NMR Spectroscopy, J. Am. Chem. Soc., 2015, 137, 13964–13971.

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41. Pinon A.C., Rossini A.J., Widdifield C.M., Gajan D., and Emsley L. Polymorphs of Theophylline Characterized by DNP Enhanced Solid-State NMR, Mol. Pharm., 2015, 12, 4146–4153.

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40. Rossini A.J., Schlagnitweit J., Lesage A., and Emsley L. High-Resolution NMR of Hydrogen in Organic Solids by DNP Enhanced Natural Abundance Deuterium Spectroscopy, J. Magn. Reson., 2015, 259, 192-198.

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39. Valla M., Rossini A.J., Caillot M., Chizallet C., Raybaud P., Digne M., Chaumonnot A., Lesage A., Emsley L., van Bokhoven J.A., and Copéret C. Atomic Description of the Interface Between Silica and Alumina in Aluminosilicates Through Dynamic Nuclear Polarization Surface-Enhanced NMR Spectroscopy and First-Principles Calculations, J. Am. Chem. Soc., 2015, 137, 10710-10719.

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38. Sangodkar R.P., Smith B.J., Gajan D., Rossini A.J., Roberts L.R., Funkhouser G.P., Lesage A., Emsley L., Chmelka B.F. Influences of Dilute Organic Adsorbates on the Hydration of Low-Surface-Area Silicates, J. Am. Chem. Soc., 2015, 137, 8096-8112.

37. D’Elia V., Dong H., Rossini A.J., Widdifield C.M., Vummaleti S.V.C., Minenkov Y., Poater A., Abou-Hamad E., Pelletier J.D.A., Cavallo L., Emsley L., and Basset J.-M. Cooperative Effect by Monopodal Surface Niobium Complexes Enhancing Cyclic Carbonate Production, J. Am. Chem. Soc., 2015, 137, 7728-7739.

36. Protesescu L., Nachtegaal M., Voznyy O., Borovinskaya O., Rossini A.J., Emsley L., Coperet C., Günther D., Sargent E.H., Kovalenko M.V. Atomistic Description of Thiostannate-Capped CdSe nanocrystals: Retention of Four-coordinate SnS4 motif and Preservation of Cd-rich Stoichiometry, J. Am. Chem. Soc.,2015, 137, 1862-1874.

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35. Kubicki D.J., Rossini A.J., Purea A., Zagdoun A., Ouari O., Tordo P., Engelke F., Lesage A., Emsley L. Amplifying Dynamic Nuclear Polarization of Frozen Solutions by Incorporating Dielectric Particles, J. Am. Chem. Soc., 2014, 135, 15711-15718.

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34. Segal-Peretz T., Jahnke J.P., Berenson A., Neeman L., Oron D., Rossini A.J., Chmelka B.F., Gitt F.L. Understanding and Promoting Molecular Interactions and Charge Transfer in Dye-Mediated Hybrid Photovoltaic Materials, J. Phys. Chem. C., 2014, 118, 25374-25391.

33. Rossini A.J., Hildebrand M.P., Hazendonk P.A., Schurko R.W. Multinuclear Solid-State NMR Studies of Polymer-Supported Scandium Triflate Catalysts, J. Phys. Chem. C., 2014, 118, 22649-22662.

32. Wolf P., Valla M., Rossini A.J., Comas-Vives A., Núñez-Zarur F., Malaman B., Lesage A., Emsley L., Copéret C., Hermans I. Spectral Signatures of the Active Sites in Sn–β Zeolite, Angew. Chem. Int. Ed., 2014, 53, 10179-10183.

31. Conley M.P., Rossini A.J., Vives A.C., Valla M., Cassano G., Ouari O., Tordo P., Lesage A., Emsley L., Copéret C. Silica Surface Reorganization During Organotin Grafting Evidenced by 119Sn DNP SENS: A Tandem Reaction of gem-silanols and Strained Siloxane Bridges, Phys. Chem. Chem. Phys., 2014, 16, 17822-17827.

30. Lelli M., Rossini A.J., Ouari O., Tordo P., Lesage A., Emsley L. Hydrophobic Radicals Embedded in Neutral Surfactants for Dynamic Nuclear Polarization of Aqueous Environments at 9.4 Tesla, Chem. Comm., 2014, 50, 10198-10201.

29. Rossini A.J., Emsley L., O’Dell L.A. Dynamic Nuclear Polarization Enhanced 14N Overtone Spectroscopy, Phys.Chem. Chem. Phys., 2014, 16, 12890-12899.

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28. Protesescu L., Rossini A.J., Kriegner D., Valla M., Reiss P., de Kargommeaux A., Walter M., Kravchyk K., Nachtegaal M., Stangl J., Malaman B., Lesage A., Emsley L., Coperet C., Kovalenko M. Unraveling the Core-Shell Structure of Organic and Inorganic Passivated Sn/SnOx Nanoparticles by Dynamic Nuclear Polarization Surface Enhanced NMR, Mossbauer and X-ray Absorption Spectroscopies, ACS Nano, 2014, 8, 2639-2648.

27. Rossini A.J., Widdifield C.M., Zagdoun A., Lelli M., Schwarzwälder M., Copéret C., Lesage A., Emsley L. DNP Enhanced NMR Spectroscopy for Pharmaceutical Formulations, J. Am. Chem. Soc., 2014, 136, 2324-2334.

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26. Samantaray M.K., Callens E., Abou-Hamad E., Rossini A.J., Widdifield C.M., Dey R., Emsley L. and Basset J.M. WMe6 Tamed by Silica: Efficient Well-Defined Catalyst ≡Si-O-WMe5 for Alkane metathesis: Synthesis and Identification of Supported W-Methylidyne Species, J. Am. Chem. Soc., 2014, 136, 1054-1061.

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25. Ferrara C., Tealdi C., Pedone A., Menziani C., Rossini A.J., Pintacuda G., Mustarelli P., Local versus average structure in LaSrAl3O7: a NMR and DFT investigation. J. Phys. Chem. C,2013, 117, 23451-23458.

24. Gajan D., Schwarzwälder M., Conley M.P., Gruening W., Rossini A.J.; Zagdoun A., Lelli M.,Yulikov M., Jeschke G., Sauvée C., Ouari O., Tordo P., Veyre L., Lesage A., Thieuleux C., Emsley L., Copéret, Christophe. Solid-phase DNP Polarizing Matrices from Homogeneously Distributed Radicals in Mesostructured Hybrid Silica Materials, J. Am. Chem. Soc., 2013, 135, 15459-15466.

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23. Conley M.P., Drost R.M., Baffert M., Gajan D., Elsevier C., Franks W.T., Oschkinat H., Veyre L., Zagdoun A., Rossini A.J., Lelli M., Casano G., Ouari O., Tordo P., Lesage A., Emsley L., Copéret C., Thieuleux C., A well-defined Pd-hybrid material for the Z-selective semi-hydrogenation of alkynes characterized at the molecular level by DNP SENS, Chem. Eur. J., 2013, 19, 12234-12238.

22. Zagdoun A., Casano G., Ouari O., Schwarzwälder M., Rossini A.J., Aussenac F., Yulikov M., Jeschke G., Copéret C., Lesage A., Tordo P., Emsley L. Design of Nitroxide Biradicals Providing Efficient Dynamic Nuclear Polarization at Temperatures up to 200 Kelvin, J. Am. Chem. Soc., 2013, 135, 12790-12797.

21. Rossini A.J., Zagdoun A., Lelli M., Lesage A., Copéret C., Emsley L. Dynamic Nuclear Polarization Surface Enhanced NMR Spectroscopy, Acc. Chem. Res., 2013, 46, 1942-1951. (Special Issue on Solid-state NMR)

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20. Grüning W.R., Rossini A.J., Gajan D., Lesage A., Emsley L., Copéret C. Molecular-Level Characterization of the Structure and the Surface Chemistry of Periodic Mesoporous Organosilicates by DNP-Surface Enhanced NMR Spectroscopy, Phys. Chem. Chem. Phys., 2013, 15, 13270-13274.

19. Rossini A.J., Macgregor A.W., Smith A.S., Schatte G., Schurko R.W., Briand G.G. Structural Variation in Ethylenediamine and -Diphosphine Adducts of (2,6-Me2C6H3S)2Pb: A Single Crystal X-ray Diffraction and 207Pb Solid-State NMR Spectroscopy Study, Dalton. Trans., 2013, 42, 9533-9546

18. Sun M., Abou-Hamad E., Rossini A.J., Zhang J., Lesage A., Zhu H., Pelletier J., Emsley L., Caps V. and Basset J.-M. Methane Reacts with Heteropolyacids Chemisorbed on Silica to Produce Acetic Acid under Soft Conditions, J. Am. Chem. Soc.,2013, 135, 804-810.

17. Zagdoun A., Rossini A.J., Conley M.P., Grüning W., Schwarzwälder M., Franks T.W., Oschkinat H., Copéret C., Lesage A., Emsley L. Improved DNP Surface Enhanced NMR Spectroscopy through Controlled Incorporation of Deuterated Functionalities, Angew. Chem. Int. Ed., 2013, 52,1222-1225.

16. Rossini A.J., Zagdoun A., Hegner F.S., Schwarzwälder M., Gajan D., Copéret C., Lesage A., Emsley L. Dynamic Nuclear Polarization NMR Spectroscopy of Microcrystalline Solids, J. Am. Chem. Soc., 2012, 134, 16899-16908. (JACS Spotlight, J. Am. Chem. Soc., 2012, 134, 17840-17841.

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15. Macdonald C.L.B., Bandyopadhyay R., Cooper, B.F.T, Friedl W., Rossini A.J., Schurko R.W., Eichhorn S., Herber R. Experimental and Computational Insights Into the Stabilization of Low-Valent Main Group Elements Using Crown Ethers and Related Ligands, J. Am. Chem. Soc., 2012, 134, 4432-4345.

14. Zagdoun A., Casano G., Ouari O., Lapadula G., Rossini A.J., Lelli M., Baffert M., Gajan D., Veyre L., Maas W.E., Rosay M., Weber R.T., Thieuleux C., Copéret C., Lesage A., Tordo P., Emsley L. A Slowly Relaxing Rigid Biradical for Efficient DNP Surface Enhanced NMR Spectroscopy: Expeditious Characterization of Functional Group Manipulation in Hybrid Materials, J. Am. Chem. Soc., 2012, 134, 2248-2291.

13. Vitzthum V., Miéville P., Carnevale D., Caporini M.A., Gajan D., Copéret C., Lelli M., Zagdoun A., Rossini A.J., Lesage A., Emsley L. and Bodenhausen G. Dynamic Nuclear Polarization of Quadrupolar Nuclei Using Cross Polarization from Protons: Surface-Enhanced Aluminum-27 NMR, Chem. Commun., 2012, 48, 1988-1990.

12. Rossini A.J., Zagdoun A., Lelli M., Canivet J., Aguado S., Ouari O., Tordo P., Rosay M., Maas W.E., Copéret C., Farrusseng D., Emsley L., Lesage A. Dynamic Nuclear Polarization Enhanced Solid-State NMR Spectroscopy of Functionalized Metal-Organic Frameworks, Angew. Chem-Int. Ed., 2012, 51, 123-127.

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11. Zagdoun A., Rossini A.J., Gajan D., Bourdolle A., Ouari O., Rosay M., Maas W.E., Tordo P., Lelli M., Emsley L., Lesage A. and Copéret C. Non-Aqueous Solvents for Surface Enhanced Dynamic Nuclear Polarization Spectroscopy. Chem. Commun., 2012, 48, 654-656. (Cover Article)

10. Rossini A.J., Zagdoun A., Lelli M., Gajan D., Rascón F., Rosay M., Maas W. E., Copéret C., Lesage A., Emsley L., One Hundred Fold Overall Sensitivity Enhancements for Silicon-29 NMR Spectroscopy of Surfaces by Dynamic Nuclear Polarization with CPMG Acquisition, Chem. Sci., 2012, 3, 108-115.

9. Rossini A.J., Hung I., Johnson S.A., Mensch M., Slebodnick, C., Deck P.A. and Schurko R.W. Solid-State 91Zr NMR Spectroscopy Studies of Zirconocene Olefin Polymerization Catalyst Precursors. J. Am. Chem. Soc., 2010, 132, 18301–18317.

8. Rossini A.J., Hung I., and Schurko R.W. Solid-state 47/49Ti NMR of Titanocene Chlorides. J. Phys. Chem. Lett, 2010, 1, 2989–2998.

7. Rossini A.J., Hamaed H., Schurko R.W. The Application of Frequency Swept Pulses for the Acquisition of Nuclear Quadrupole Resonance Spectra. J. Magn. Reson., 2010, 206, 32–40.

6. Bandyopadhyay, R., Cooper, B.F.T., Rossini, A.J., Schurko, R.W., Macdonald, C.L.B. Crown Ether Complexes of Tin(II) Trifluoromethane-sulfonate. J. Organomet. Chem., 2010, 695, 1012–1018.

5. Rossini A.J., Mills R.W., Briscoe G.A., Norton E.L., Geier S.J., Hung I., Zheng S., Autschbach J., Schurko R.W. Solid-State Chlorine NMR of Group IV Transition Metal Organometallic Complexes. J. Am. Chem. Soc., 2009, 131, 3317–3330.

4. O’Dell L.A., Rossini A.J., and Schurko R.W. Acquisition of Ultra-Wideline NMR Spectra from Quadrupolar Nuclei by Frequency-Stepped WURST-QCPMG. Chem. Phys. Lett., 2009, 468, 330-335.

3. Briand G.G., Smith A.D., Schatte G., Rossini A.J., Schurko R.W. Probing Lead(II) Bonding Environments in 4-Substituted Pyridine Adducts of (2,6-Me2C6H3S)2Pb: An X-ray Structural and Solid-State 207Pb NMR Study. Inorg. Chem., 2007, 46, 8625-8637.

2. Rossini A.J. and Schurko R.W. Experimental and Theoretical Studies of 45Sc NMR Interactions in Solids. J. Am. Chem. Soc., 2006, 128, 10391-10402.

1. Hung I., Rossini A.J., and Schurko, R.W. Application of the Carr-Purcell Meiboom-Gill Pulse Sequence for the Acquisition of Solid-State NMR Spectra of Spin-1/2 Nuclei. J. Phys. Chem. A, 2004, 108, 7112-7120.